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化学工业:2016 -声学和1 H NMR酸性核与一些极性液体萃取剂的反应——Biswajit达赖

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东方科技学院,印度超声波速度、厚度和一致性的酸性原子萃取剂特别是di (2-ethylhexyl)磷酸腐蚀(D2EHPA)及其与三个一元羧酸即双混合,酸,丙和n-butyric估计温度T = 303.15 K和压力,P = 0.1 mpa。探索性的信息被用来解除注册时间,亚原子关系稳定,在分子间自由长度偏差,声阻抗,自由体积和熵变,过多吉布颁布的活力粘性流,丰富整个摩尔焓部分D2EHPA的范围。过多/偏差的能力被安装Redlich-Kister多项式型条件来衡量配对测试和决定系数和标准错误信息。这些能力被用来猜亚原子粒子部分关联的想法考虑并行混合。此外,1 H NMR谱的纯粹的D2EHPA与一元羧酸及其并行混合原子之间的通信是利用调查的部分流体混合在微小的水平,证明从质量特性获得的结果。厚度、超声波速度和一致性的有机磷萃取剂,例如di (2-ethylhexyl)磷酸腐蚀(D2EHPA)及其与五个平行混合烷醇(C1-C4 C8)即,甲醇,乙醇,1-propanol 1-butanol和1-octanol估计为303.15 K和气候的重量。利用这些测试独秀,丰富摩尔体积,过多吉布斯活力颁布的粘性流,偏差在超声波速度、厚度、等熵压缩,分子间自由长度和声阻抗在整个摩尔已登记部门D2EHPA的范围。这些丰富/偏差能力被安装Redlich-Kister多项式条件推断出双重的系数和衡量标准测试和确定之间的错误信息。过多的品种/偏差能力失效D2EHPA已经检查到亚原子合作混合。此外,1 h NMR谱的双重混合在一个稳定的体积占和相关的声学反应。 In this work, 1H NMR relaxometry and diffusometry just as viscometry tests were done as a way to examine the sub-atomic elements of attractive and nonmagnetic ionic fluid based frameworks. So as to assess the impact of a cosolvent on the superparamagnetic properties watched for Aliquat-iron-based attractive ionic fluids, blends involving various focuses, 1% and 10% (v/v), of DMSO-d6 were arranged and examined. The outcomes for both attractive and nonmagnetic frameworks were reliably dissected a recommend that, when at low fixations, DMSO-d6 advances progressively organized ionic plans, in this way improving these superparamagnetic properties. Besides, the examination of temperature and water fixation impacts permitted to presume that neither one of these factors essentially influenced the superparamagnetic properties of the considered attractive ionic fluids. biswajit.dalai@eastodissa.ac.in

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