ISSN: 2321 - 6212
合成方面以外的分布式电化学系统:从电流电压发电机,Bio-cells,电池和蓄电池在合成发射和辐射效应,等等
最近的实验和数值研究燃烧硫化物的合成(CSS)结合当前的固体电子理论(ETSB)引导我们得出的结论是,CSS硫化内化学反应都伴随着电子转换价区,即通过电子的能量状态之间的转换价带的本地化。这样的结论只能解释能量的巨大的差异硫硫集群关联一个电子的电离势可用在文学。除了CSS和ETSB的相互关联的方面我们也提出了一个小回顾现有的文献电化学电流和电压的来源(细胞、蓄电池)。本文致力于分布式电化学系统,在一定程度上补充一些早期的评论写(与作者的参与)基于她完全的电力来源。雷竞技苹果下载作为结果,它已经取得了优势的结论基于燃烧源的电流(烟火的电流源,微微秒)与现代蓄电池和bio-cells相比。微微秒稳定工作的条件进行了讨论。顺便说一下我们也考虑一些工作材料合成和纳米颗粒。纳米粒子现在非常流行。文章的作者关于这样的外来物体在他们的出版物中经常使用不合理的近似或/和无节制的事实。在我们看来,读者意识到,和类似的什么结论作者偏离现实或从古典结果之前收到。 To prove a solvency and a coherence of new results and representations is the business of innovators themselves, not of others or us. We just reveal some of their frequent shortcomings here. The comparison of the SHS systems on the specific electric energies generated during the synthesis has been also carried out. The energies appear to depend strongly on the composition, green density and the sample electric resistance. We have shown that in the SHS semiconductive systems of a loosed density (SLD) the generated specific electric energy is comparably less than that of a fish slope. Therefore, We have suggested new non-system units based on the specific electric energy generated by a fish slope as a useful measure for the SLD generated electric energies. It has appeared that the greatest quantity of specific electric energy is emitted by the loosed mixture of titanium with its nitride. Nevertheless, We have calculated that even the titanium nitride mixtures contain the overwhelming part of their energy in that of a chemical type (as the enthalpy of the green mixture formation). Both in compact and in SLD systems the specific standard enthalpies of formation of green components or products exceed significantly the electric energy released. Any source of electric voltage or electric current based on the combustion synthesis cannot be compared by the efficiency to electrolytic accumulators (their efficiency is close to unit by the definition). Therefore, We have also considered the general principles of association of such sources into batteries. It is well known that exoemission of electrons (EE) is an inevitable condition of any solid body existence in Nature. Nevertheless, there is still no clear understanding of high energetic EE caused by some of SHS processes. We have given the estimate confirming the possibility of high energetic electrons to be emitted during SHS, reveal the most perspective SHS systems in this relation, and simultaneously discuss the problems of chemically stimulated exoemission of electrons (CSEE) existing now in our opinion.
Filimonov IA